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2.3.2.1 Catalyzed ROP Reactions of Bridged Ferrocenes ROP of strained-ring organometallics is not limited to thermal reactivity. Anionic initiators, such as n-BuLi, allow the synthesis of living poly(ferrocenylsilane) derivatives in THF at room temperature with controlled molecular weights and narrow polydispersities. However, pure reactants and solvents are necessary. Block copolymers of 1,10 -dimethylsilane-bridged ferrocene and [(CH3 )2 SiO]3 , both of which have ring strain, are possible using this anionic ROP living polymerization method (see Fig. 2.34). Block copolymers of poly(ferrocene) derivatives and organic polymers provide redox-active domains in solid-state spheres, cylinders, lms, and micelles (60). Transition metal-catalyzed ROP of organosilyl-bridged [1]ferrocenophanes provides another method of synthesizing polymers and block copolymers without the necessity of an ultrapure monomer. The mechanism or mechanism of the catalytic reactions using rhodium(I), palladium(II), and platinum(II) as well as palladium(0) and platinum(0) has been undergoing investigation for some time, and the current indication is that the catalysts are colloidal noble metals (61). SnR2 bridged ferrocenophanes do not undergo platinum-catalyzed ROP but can be catalyzed by bases such as amines (62). In fact, impure products of R2 Snbridged [1]ferrocenophane from preparations that involve amines can undergo slow ROP even at room temperature (62). Thus it is possible that the so-called thermal ROP reactions noted above are catalyzed by traces of amines left in other ferrocenophanes as well (62). Hydrophilic water-soluble neutral and cationic poly(ferrocenylsilanes) of high molecular mass have been synthesized at room temperature by

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10 Jul 2018 ... QR stands for Quick Response; it's a type of two-dimensional barcode that is used to store small amounts of text or data. It was created by the ...

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Some of the equations used to determine the intrinsic viscosity (the viscosity as zero concentration) of inorganic polymer solutions are as follows: r D / 0 D t/t0 3.18

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ASYNCHRONOUS TRANSFER MODE (ATM)

1 (t t1 )2 (t tm 1 )2 (t tm )f (2m 1) ( ), (2m 1)! (5.25)

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< cue is shown less by liars than by truth tellers > cue is shown more by liars than by truth tellers no differences was found between liars and truth tellers Empty cells mean that the cue was not investigated DePaulo, Lindsay et al. (2003) did not investigate consistencies or contradictions

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